Product ID:839 7929,KODAK FLEXICOLOR RA BLEACH REPLENISHER NR
MSDS Date:01/09/1998
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKMGM

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

WATER

CAS: 7732-18-5

RTECS: ZC0110000

FERRIC AMMONIUM PROPYLENEDIAMINETETRAACETIC ACID

CAS: 111687-36-6

AMMONIUM BROMIDE

CAS: 12124-97-9

RTECS: BO9155000

AMMONIUM NITRATE

CAS: 6484-52-2

RTECS: BR9050000

ACETIC ACID

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1,3-PROPYLENEDIAMINETETRAACETIC ACID

CAS: 1939-36-2

Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: GENERAL:
CONTAINS: FERRIC AMMONIUM PROPYLENEDIAMINETETRAACETIC ACID &
1,3-PROPYLENEDIAMINETETRAACETIC ACID. EXPOSURE TO HIGH
CONCENTRATIONS MAY CAUSE INCREASED URINARY EXCRETION O F ZINC AND
CALCIUM. INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED
HANDLING. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE):INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE N ATIONAL
TOXICOLOGY PROGRAM (NTP): NONE OCCUPATIONAL SAFETY AND HEALTH
ADMINSTRATION (OSHA): NONE.
Effects of Overexposure:EXPOSURE TO HIGH CONCENTRATIONS MAY CAUSE
INCREASED URINARY EXCRETION OF ZINC AND CALCIUM. EYES: CAUSES
IRRITATION. SKIN: CAUSES IRRITATION.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH
CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEAN
CONTAMINATED SHOES. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK
MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.

Flash Point:NONE.
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG OXIDIZER.
DRIED PRODUCT RESIDUE CAN ACT AS AN OXIDIZER. FIRE OR HIGH
TEMPERATURES MAY CAUSE DECOMPOSITION.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUA L CONTAMINATION.

Handling and Storage Precautions:KEEP AWAY FROM INCOMPATIBLE
SUBSTANCES. STORE IN ORIGINAL CONTAINER. KEEP CONTAINER TIGHTLY
CLOSED TO PREVENT THE LOSS OF WATER. DO NOT STORE OR SHIP TOGETHER
WITH COMBUSTIBLE MATERIAL. KEEP FROM CONT ACT WITH OXIDIZING
MATERIALS. WASH CONTAMINATED CLOTHING. KEEP AWAY FROM HEAT.
Other Precautions:IF ACCIDENTALLY MIXED WITH A STRONG OXIDIZER OR ACID,
DO NOT BREATHE GAS. AVOID BREATHING MIST OR VAPOR. AVOID CONTACT
WITH EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFT ER HANDLING.KEEP AWAY FROM INCOMPATIBLE SUBSTANCES
(SEE INCOMPATIBILITY SECTION).

Respiratory Protection:NONE SHOULD BE NEEDED UNDER NORMAL CONDITIONS OF
USE.HOWEVER IN THE UNLIKELY EVENT THAT HAZARDOUS DECOMPOSITION
PRODUCTS ARE RELEASED, EMERGENCY RESPONSE PERSONNEL MUST WEAR A
FULL-FACE POSITIVE-PRESS URE AIR SUPPLIED RESPIRATOR. IF
RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES APPROPRIATE FOR THE RISK OF
EXPOSURE.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK
OF EXPOSURE. EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
Supplemental Safety and Health
NONE

HCC:C3
Boiling Pt:>100.C, 212.F
Decomp Temp:>215.C, 419.F
Vapor Pres:(68F) 24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:(WATER = 1): 1.17
pH:3.5
Solubility in Water:COMPLETE
Appearance and Odor:PHYSICAL FORM: LIQUID COLOR: GREEN - BROWN ODOR:
SLIGHT ACETIC ACID.
Percent Volatiles by Volume:60-65 % WT

Stability Indicator/Materials to Avoid:YES
BASES, STRONG OXIDIZING AGENTS (E.G. SODIUM HYPOCHLORITE (BLEACH) ),
COMBUSTIBLE MATERIAL, STRONG REDUCING AGENTS. CONTACT WITH BASE
LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:HOWEVER, MATERIAL CAN DECOMPOSE ABOVE 215C
(419F). AVOID TEMPERATURES ABOVE 115C (239F).
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, HYDROGEN BROMIDE AMMONIA, CHLORAMINE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER.

Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS:
FERRIC AMMONIUM PROPYLENEDIAMINETETRAACETIC ACID &
1,3-PROPYLENEDIAMINETETRAACETIC ACID. EXPOSURE TO HIGH
CONCENTRATIONS MAY CAUSE INCREASED URINARY EXCRETION O F ZINC AND
CALCIUM. INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED
HANDLING. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:MODERATELY ACIDIC SOLUTION. MAY CAUSE ADVERSE ENVIRONMENTAL
EFFECTS. IT IS EXPECTED TO HAVE FOLLOWING: A LOW BIOCHEMICAL OXYGEN
DEMAND AND LITTLE POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS
SYSTEMS , A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS, A LOW
POTENTIAL TO AFFECT SECONDARY WASTE TREATMENT MICROBIAL METABOLISM,
A HIGH POTENTIAL TO AFFECT GERMINATION AND/OR EARLY GROWTH OF SOME
PLANTS, A HI GH POTENTIAL TO PHOTOCHEMICALLY/CHEMICALLY DEGRADE, A
LOW POTENTIAL TO BIOCONCENTRATE. AFTER DILUTION WITH A LARGE AMOUNT
OF WATER, FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS
NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: NITRATE COMPOUNDS (WATER DISSOCI ABLE) (AMMONIUM NITRATE)
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE